There are two simple ways to backup only the users and privileges in MySQL:

1- Using mysqlpump utility (as create user and grant statements):

[shell ~]$ mysqlpump -uUSER -p --exclude-databases=% --add-drop-user --users > /tmp/pump-all-users_privileges-timestamp.sql
Dump completed in 1364 milliseconds

Sample output:

[shell ~]$ head /tmp/pump-all-users_privileges-timestamp.sql
Continue reading →